Yes. You will create a 4-digit PIN (personal identification number) when you activate your personalized card. Use this PIN and select "Checking" when making the withdrawal. You may only make withdrawals from ATMs in the U.S. due to fraud or security concerns. Log in to see your Account Agreement for ATM withdrawal limits.
Log in to your account using the Green Dot app or on GreenDot.com to find an ATM location near you.